【英文标准名称】:Plastics-Determinationofaveragemolecularmassandmolecularmassdistributionofpolymersusingsize-exclusionchromatography-Universalcalibrationmethod
【原文标准名称】:塑料.用粒度排除色谱法测定聚合物的平均分子量和分子量的分布.通用校准法
【标准号】:BSISO16014-2-2003
【标准状态】:作废
【国别】:英国
【发布日期】:2003-05-16
【实施或试行日期】:2003-05-16
【发布单位】:英国标准学会(GB-BSI)
【起草单位】:BSI
【标准类型】:()
【标准水平】:()
【中文主题词】:质量(物质);测量原理;分子;平均;校正;测量方法;大小测量;原理;分子质量;色谱法;胶体渗透色谱法;定义;方法;塑料;测量技术;测定
【英文主题词】:Average;Calibration;Chromatography;Definition;Definitions;Determination;Gelpermeationchromatography;Mass;Measuringtechniques;Methods;Methodsformeasuring;Molecularmass;Molecules;Plastics;Principle;Principleofmeasurement;Sizemeasurement
【摘要】:ThispartofISO16014specifiesamethodfordeterminingtheaveragemolecularmassandthemolecularmassdistributionofpolymersusingsize-exclusionchromatography(SEC).Theaveragemolecularmassandthemolecularmassdistributionarecalculatedusingauniversalcalibrationcurveinsteadoftheconventionalcalibrationcurve.TheconceptoftheuniversalcalibrationmethodisbasedonarelationshipbywhichtheretentiontimeinSECdependsonthesizeofthepolymermolecule(thehydrodynamicvolume)orontheproductoftheintrinsicviscosity[η]andthemolecularmassM.Manypolymersclassifiedasrandom-coilpolymers(regardlessoftheirchemicalstructure,degreeofbranching,compositionortacticity)havebeenexperimentallyconfirmedasfollowingthisrelationship.Theuniversalcalibrationcurveisconstructedbyplottingthelogarithmof[η]MversustheelutiontimetorelutionvolumeVusingpolymerstandardssuchaspolystyrenewithnarrowmolecularmassdistributions.ThemolecularmassMiofanunknownpolymersamplecanthenbecalculatedfromthevalueof[η]Mateachretentiontimeusingtheuniversalcalibrationcurveand[η]orKandaintheMark-Houwink-Sakuradaequation([η]=KM→[η]M=KM,whereKisaconstantandaisanexponentdependingontheexperimentalconditions.ThereforethistestmethodisclassifiedasarelativemethodasdescribedinISO16014-1,buttheaveragemolecularmassesandmolecularmassdistributionscalculatedbythemethodareequalto,ornearlyequalto,theabsolutevalues.AlistofdocumentsrelatedtothispartofISO16014isgivenintheBibliography.
【中国标准分类号】:G31
【国际标准分类号】:83_080_01
【页数】:20P;A4
【正文语种】:英语